In a 12-inch skillet with a lid, heat olive oil over medium heat.
Sprinkle the Old Bay on each side of the pork chops, reserving 1 teaspoon of seasoning for later.
Pan sear the chops, about 2-3 minutes on each side. You aren't looking for doneness here, just a good color. When both sides are golden remove form skillet and set aside.
Add in chopped onion, bell pepper and let cook for about 1 minute.
Pour the can of tomatoes and green chiles, and the undrained can of black eyed peas. Stir in the broth, rice, worcestershire sauce , and last teaspoon of Old Bay. Top with pork chops.
Bring mixture to a simmer. Place lid on skillet and turn down to low. Let simmer 25 minutes until all liquid is absorbed.